FTIR absorption spectra of ClCS in an argon matrix

✍ Scribed by Günter Schallmoser; Brent E. Wurfel; Anton Thoma; Nico Caspary; Vladimir E. Bondybey

• Publisher: Elsevier Science
• Year: 1993
• Tongue: English
• Weight: 587 KB
• Volume: 201
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(93)85112-2

✦ Synopsis

ClCS was produced with a pulsed jet-dc discharge of ClaCS/Ar, CS2/ClJAr, and CS,/CCI,/Ar and deposited forming an argon matrix. The vibrational frequencies for Y, and v, are determined to be 1189.3 and 632.1 cm-', respectively. Isotopic substitution experiments and normal coordinate calculations were performed to confirm the assignments.