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FT-IR study of the structure and reactivity of methoxy species on ThO2 and CeO2

✍ Scribed by Lamotte, J. ;Morávek, V. ;Bensitel, M. ;Lavalley, J. C.

Book ID
112686595
Publisher
Springer
Year
1988
Tongue
English
Weight
226 KB
Volume
36
Category
Article
ISSN
0133-1736

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High-valence osmium ions (OS'+ or 0s" ) were stabilized on CeOz and Th02, when the initially impregnated cluster OSCAR was decomposed under oxidizing conditions. This is in contrast to the formation of low-valence ions (OS'+ and 0~~') on Al,03. The presence of osmium on Ce02 and Th02 presumably modi