FT-IR determinations in charge-transfer interactions between phenylhydrazones and organic acceptors
✍ Scribed by Bruni, Paolo ;Cardellini, Liberato ;Tosi, Giorgio
- Book ID
- 105165372
- Publisher
- Springer-Verlag
- Year
- 1988
- Weight
- 125 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0344-838X
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## Abstract Poly(γ‐benzyl‐L‐glutamate) having a terminal dimethylaminoanilide group as an electron donor (D) and a terminal 3,5‐dinitrobenzoyl group as an electron acceptor (A) (A‐[Glu(OBzl)]~__n__~‐D) was synthesized by the __N__‐carboxyanhydride method. Polymer samples were fractionated by gel ch
The enthalpies of formation for charge transfer complexes of the type [R&1.1,] (R = CH3, C2F5, n-C3H,, n-&H,) have been measured by calorimetry. The data are analysed using Mulliken's resonance structure theory, to produce the different energy contributions to the formation ofand the charge transfer