From olefin cyclopropanation to olefin m
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A. F. Noels; A. Demonceau
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Article
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1998
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John Wiley and Sons
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English
⚖ 173 KB
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An overview of the recent synthetic breakthroughs brought about by the discovery of new, functional group tolerant late transition metal (Rh and Ru)-based catalysts is proposed. Whereas dirhodium(II)-based complexes promote only carbene transfer reactions to olefins (i.e. olefin cyclopropanation), a