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From crystal to crystal: A reconstructive solid-state reaction

✍ Scribed by Trixie Wagner; Uwe Eigendorf; Gerhard E. Herberich; Ulli Englert

Book ID
105522436
Publisher
Springer
Year
1994
Tongue
English
Weight
377 KB
Volume
5
Category
Article
ISSN
1040-0400

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Albert Eschenmoser on the occasion of his 75th birthday Upon warming to 225 K, single crystals of 11-bromoundecanoyl peroxide (BrUP), in which radicals have been created by photolysis at lower temperature, undergo partial decomposition by a radical chain reaction ca. 40 cycles long. FTIR allowed mon