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A Single Crystal Study of a Solid-state Polymerization Reaction

✍ Scribed by O. Herzberg; M. Epple


Book ID
110287859
Publisher
Springer Netherlands
Year
1999
Tongue
English
Weight
92 KB
Volume
57
Category
Article
ISSN
0022-5215

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Albert Eschenmoser on the occasion of his 75th birthday Upon warming to 225 K, single crystals of 11-bromoundecanoyl peroxide (BrUP), in which radicals have been created by photolysis at lower temperature, undergo partial decomposition by a radical chain reaction ca. 40 cycles long. FTIR allowed mon