The Grubbs' mthenium-carbene complexes, RuCI2(=CHPh)(PR3)2, mediate the Kharasch addition of CC14 across olefins, and the controlled atom transfer radical polymerisation of vinyl monomers with high yields and selectivities which markedly depend on the phosphine iigands of the complex (R=phenyl, cycl
β¦ LIBER β¦
From atom transfer radical addition to atom transfer radical polymerisation of vinyl monomers mediated by ruthenium indenylidene complexes
β Scribed by Opstal, Tom; Verpoort, Francis
- Book ID
- 121393961
- Publisher
- Royal Society of Chemistry
- Year
- 2002
- Tongue
- English
- Weight
- 891 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1144-0546
- DOI
- 10.1039/B210040A
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