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Kharasch addition and controlled atom transfer radical polymerisation (ATRP) of vinyl monomers catalysed by Grubbs' rutheniumcarbene complexes

✍ Scribed by François Simal; Albert Demonceau; Alfred F. Noels

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
275 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Grubbs' mthenium-carbene complexes, RuCI2(=CHPh)(PR3)2, mediate the Kharasch addition of CC14 across olefins, and the controlled atom transfer radical polymerisation of vinyl monomers with high yields and selectivities which markedly depend on the phosphine iigands of the complex (R=phenyl, cyclopentyl, and cyclohexyl).

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