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Fries rearrangement of the benzenesulphonates of xylenols

✍ Scribed by V. Baliah; Miss M. Uma

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
378 KB
Volume
80
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The benzenesulphonates of xylenols undergo isomerisation when heated with anhydrous aluminium chloride, giving hydroxy‐sulphones, the structures of which have been established.

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## Abstract The rearrangement of 1‐naphthyl acetate in nitrobenzene solution, catalysed by aluminium chloride, to give 2‐ and 4‐acetylnaphthol, appears to be intramolecular in nature. A mechanism to account for the experimental results is proposed. While the main product is the __p__‐hydroxy‐ketone