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The fries rearrangement of 1-naphthyl acetate

✍ Scribed by N. M. Cullinane; V. V. Bailey-Wood

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
246 KB
Volume
78
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The rearrangement of 1‐naphthyl acetate in nitrobenzene solution, catalysed by aluminium chloride, to give 2‐ and 4‐acetylnaphthol, appears to be intramolecular in nature. A mechanism to account for the experimental results is proposed. While the main product is the p‐hydroxy‐ketone, moderate yields of the ortho‐substituted product are also obtained.

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