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Friedel-Crafts Reactions of Vinylaziridine Linked to an Ester Group

✍ Scribed by Nagumo, Shinji; Takada, Hisashi; Yasui, Eiko; Sahara, Yui; Chinen, Yūki; Tanaka, Hirotoshi; Morita, Yusuke; Kobiki, Chihiro; Narisawa, Daiki; Mizukami, Megumi; Miyashita, Masaaki

Book ID
118272862
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2011
Tongue
English
Weight
814 KB
Volume
83
Category
Article
ISSN
0385-5414

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📜 SIMILAR VOLUMES

ChemInform Abstract: Friedel—Crafts Reac
ChemInform Abstract: Friedel—Crafts Reactions of Vinylaziridine Linked to an Ester Group.
✍ Shinji Nagumo; et al. et al. 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 49 KB

## Abstract The Friedel—Crafts reaction of aziridines (V) with arenes (VI) proceeds regioselectively to afford amino esters (VII), whilst the reaction with 1,4‐dimethoxybenzene (VIII) leads to an inseparable mixture of regioisomers (IX) and (X).

Introduction of an arylthio(trimethylsil
Introduction of an arylthio(trimethylsilyl)methyl group into arenes by friedel-crafts reaction: synthesis of arylmethyltrimethylsilanes
✍ Hiroyuki Ishibashi; Hiroshi Nakatani; Yoshizumi Umei; Masazumi Ikeda 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 111 KB

Friedel-Crafts reactions of [arylthio(chloro)methyl]trimethylsilanes (ti,&) with arenes gave [aryl(arylthio)methyl]trimethylsilanes (a,b>, which were converted into arylmethyltrimethylsilanes (3) by reduction with Raney nickel. Arylmethyltrimethylsilanes (3) are versatile intermediates in organic sy