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Friedel-crafts polymers—5. Evaluation of rate constants in the p-di(chloromethyl)benzene/diphenyl methane system

✍ Scribed by N. Grassie; I.G. Meldrum

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 677 KB
Volume: 7
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(71)90013-9

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✦ Synopsis

Al)sI~et--The application of a computer program to the copolymerization of p-di(chloromethyl) benzene with diphenylmethane has enabled a detailed kinetic analysis to be made. Computed results satisfactorily fit experimental observations and provide information about intermediate products which could not be observed directly. In addition, it has been possible to calculate molecular structural features such as extent of branching,

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Friedel-crafts polymers-VI evaluation of rate constants in the p-DI(chloromethyl) benzene/benzene system

✍ N. Grassie; I.G. Meldrum 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 637 KB

Extension of the study of the kinetics of the condensation polymerization of p-di(chloromethyl)benzene and benzene beyond the limitations imposed by gas chromatography has been made possible by the application of a computer-based method to experimental results obtained using gel permeation chromatog