Free-volume evolution in the system polycarbonate–polycaprolaptone studied by positron annihilation spectroscopy
✍ Scribed by J. del Río; J. Serna; F. Plazaola; J.J. Iruin; J.L. Nazabal
- Book ID
- 117145047
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 67 KB
- Volume
- 287
- Category
- Article
- ISSN
- 0022-3093
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Ah&met-The method of positron annihilation was used to study changes of free volume in polycarbonate. Annealing at 180°C and pressure 808 MPa causes significant changes of free volume (-23%) compared to nonannealed polycarbonate. The free volume compressibility was estimated to be -3.10-' MPa-'. The
## Abstract The positron annihilation lifetime spectroscopy (PALS) technique is used to measure volume relaxation in physically aged glassy polycarbonate. The relaxation times and activation energy calculated for the isothermal relaxations in the aged polycarbonate are greater than those parameters