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Free radical vs ionic additions of halogen azides to olefins

✍ Scribed by Alfred Hassner; Fred Boerwinkle

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
171 KB
Volume
10
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Free radical additions of bis(Trihalomet
Free radical additions of bis(Trihalomethyl) sulfones to olefins.
✍ Charles J. Kelley; Marvin Carmack πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 267 KB

The recent report of the alkylation and subsequent debromination of bis(tribromomethy1) sulfone,2i, with trivalent phosphorus reagents provides an elegant route to dialkyl thiirene dioxides and thus to dialkyl acetylenes.

Free radical addition of 1,3,5 - trioxan
Free radical addition of 1,3,5 - trioxan to olefins
✍ I. Rosenthal πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 78 KB

In a recent publication (1) we have reported the light-induced addition of acetals to olefins which led to the corresponding monoalkyl acetal derivatives. We report now the peroxide-induced addition of 1.3,5-trioxan to olefins at elevated temperatures.

Free-radical addition to olefins of an H
Free-radical addition to olefins of an H2S equivalent: Triphenylsilanethiol
✍ Bruno HachΓ©; Yves Gareau πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 210 KB

The tr&benyLsnytbiyl dical gcperated dmnally (AIBN-I or pbmdmnicalty in tbe pmsemce ofan olefin yields tbe anti-Vv H$ addua after-by aitltwmacek add (TFA).