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Free radical ring expansion and spirocyclization of 1,3-diketone derivatives

โœ Scribed by Wei Xu; Jian-Ping Zou; Xue-Jun Mu; Wei Zhang

Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
168 KB
Volume
49
Category
Article
ISSN
0040-4039

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Free radical ring expansion and rearrang
Free radical ring expansion and rearrangement of large carbocyclic rings
โœ Paul Dowd; Soo-Chang Choi ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 249 KB

Free radical initiated ring expansion of twelve-, thirteen-, and fourteen-membered carbocyclic rings is described together with a new synthesis of (R)-(-)-muscone. Free radical-initiated ring expansion affords entry to medium-ring carbocycles and heterocycles otherwise difficultly obtained 1ZJ The