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Free Radical Ring Expansion and Chain Extension of 1,3-Diketones.

✍ Scribed by Xue-Jun Mu; Jian-Ping Zou; Zhi-Tao Wang; Wei Zhang


Publisher
John Wiley and Sons
Year
2005
Weight
23 KB
Volume
36
Category
Article
ISSN
0931-7597

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Free radical ring-opening polymerization of 2-methylene-1,3-dioxepane (MDP) in the presence of 2,2,6,6-tetramethyl-1-piperidinyloxy free radical (TEMPO) has been achieved to afford a chain polyester (PMDP) with di-t-butyl peroxide (DTBP) as an initiator at 125ЊC. The polydispersity of the polymers d