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Free-radical reactions of some phenylthio-2,3-dideoxyhex-2-enopyranosides

✍ Scribed by J.L Marco-Contelles; C Fernández; Ana Gómez; N Martín-León

Book ID
104222102
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
297 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

The free-radical reaction of some phenylthio-2,3-dideoxyhex-2-enopyranosides with allyltri-n-butyl stannane has been studied.

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The reaction of 2-hydroxyglycal esters w
The reaction of 2-hydroxyglycal esters with alcohols in the presence of N-iodosuccinimide, stereoselective synthesis of α anomers of alkyl 3-deoxyhex-2-enopyranosides and 3,4-dideoxyhex-3-enopyranosid-2-uloses
✍ Oscar Varela; Griselda M. de Fina; Rosa M. de Lederkremer 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 681 KB

Reaction of 2,3,4,6-tetra-O-acetyl-1,5-anhydro-o-arubino-hex-l-enitol (1; 2hydroxyglucal tetraacetate) with 1.0-1.5 mol of primary, secondary, or tertiary alcohols, in the presence of 0.1-1.0 mol of N-iodosuccinimide (NIS) in acetonitrjle as solvent, afforded the a anomers of alkyl 3-deoxyhex-2-eno