Free-radical polymerization of vinyl acetate retarded by 2-furoic acid
β Scribed by J. Rieumont; N. Davidenko
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 326 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0323-7648
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Pure 1,2-addition polymers, poly(2-methylene-1,3-dioxolane), 1b, poly(2methylene-1,3-dioxane), 2b, and poly(2-methylene-5,5-dimethyl-1,3-dioxane), 3b, were prepared using the cationic initiators H 2 SO 4 , TiCl 4 , BF 3 , and also Ru(PPh 3 ) 3 Cl 2 . Small ester carbonyl bands in the IR spectra of 1
## Abstract Copperβmediated atom transfer radical polymerization (ATRP) is versatile for living polymerizations of a wide range of monomers, but ATRP of vinyl acetate (VAc) remains challenging due to the low homolytic cleavage activity of the carbonβhalide bond of the dormant poly(vinyl acetate) (P