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Free-radical polymerization of styrene in worm-like micelles

✍ Scribed by F. Becerra; J.F.A. Soltero; J.E. Puig; P.C. Schulz; J. Esquena; C. Solans

Publisher
Springer
Year
2003
Weight
466 KB
Volume
282
Category
Article
ISSN
0340-255X

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The free-radical polymerization of styrene has been studied in the homogeneous phase of supercritical (sc) CO 2 at 80 8C and pressures between 200 and 1 500 bar. 2,29-Azobisisobutyronitrile is used as initiator and CBr 4 as chain-transfer agent. The polymerization is monitored by means of online FT-