Free radical polymerization of styrene in dioctadecyldimethylammonium bromide vesicles
β Scribed by Jenci Kurja; Roeland J.M. Nolte; Ian A. Maxwell; Anton L. German
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 667 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0032-3861
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The free-radical polymerization of styrene has been studied in the homogeneous phase of supercritical (sc) CO 2 at 80 8C and pressures between 200 and 1 500 bar. 2,29-Azobisisobutyronitrile is used as initiator and CBr 4 as chain-transfer agent. The polymerization is monitored by means of online FT-
## Abstract **Summary:** Modeling of polystyrenes (PS) with various stereosequences in the narrow cylindrical channels corresponding to those found in __Ξ³__βcyclodextrin inclusion compounds (CD ICs) has been conducted. Based on the conformational modeling of stereoisomeric polystyrenes (PSs) in nar