Free Radical Displacement Processes: Reactions of CH 3 and CD 3 Radicals with Crotonaldehyde and with Methyl Propenyl Ketone 1
โ Scribed by Pitts, J. N.; Thompson, D. D.; Woolfolk, R. W.
- Book ID
- 126892074
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 632 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Using a relative rate method, rate constants for the gas-phase reactions OF the NO, radical with methacrolein and methyl vinyl ketone were determined to be ( 4 4 2 1.7) X cm' molecule-' s-' and < 6 X cm3 molecule-' S S ' , respectively, at 296 ? 2 K. The molar formation yields of rnethacrolein and m
The 1,fbutadiene radical cation reacts with acrolein and methyl vinyl ketone to produce 'stable' adducts. The nature of the reaction and the structures of the adducts were investigated by collisional activation decomposition (CAD) combined with tandem mass spectrometry (MS/MS), and also by Fourier t