Desorption of free radicals from particles can cause an emulsion polymerization system to deviate from Smith-Ewart case I1 kinetics. A mechanistic model has been developed to predict the effect of desorption of radicals from particles on the kinetics of semibatch emulsion polymerization of methyl ac
β¦ LIBER β¦
Free radical desorption in continuous emulsion polymerization
β Scribed by R.W. Thompson; J.D. Stevens
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 607 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-2509
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## Abstract One of the most important events in freeβradical emulsion polymerization is desorption of radicals from the polymer particles to the aqueous phase. Desorption takes place by diffusion of radicals inside the particle toward the surface and transfer to the aqueous phase. The rate of desor