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Free radical cyclization reactions of allylsulfonyl substituted N-aryl amide derivatives

โœ Scribed by Chuang, Che-Ping; Tsai, An-I; Tsai, Ming-Yi

Book ID
120008878
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
471 KB
Volume
69
Category
Article
ISSN
0040-4020

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AbstractรFree radical cyclization reactions of alkylsulfonyl and alkylthio substituted aromatic amide derivatives are described. Carbon radicals can be generated efยฎciently from the sulfonyl radical induced reaction of allylsulfones or the oxidation of carbonyl compounds with manganese(III) acetate.

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Benzenesulfonyl radical can be generated from sodium benzenesulfinate in aqueous acetic acid or formic acid. A benzenesulfonyi radical induced radical reaction of tt~-allylsulfonylalkyl substituted aromatic and heteroaromatic derivatives is described. Alkyl radicals can be generated efficiently from