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Free Radical Aromatic Substitution. IV. The Reaction of Acyl Peroxides with Benzotrihalides 1

✍ Scribed by Dannley, Ralph L.; Sternfeld, Marvin

Book ID
124050757
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
614 KB
Volume
76
Category
Article
ISSN
0002-7863

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Benzoyl and lauroyl peroxides undergo induced decomposition by 2,2,6,6\_tetramethylpiperidinyl-1-oxy to form acyloxy radicals and carboxylic acid in equimolar amounts. Formation of the carboxylic acid does not involve free acyloxy radicals. In connection with studies of the interaction of vinyl mon