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Aromatic Substitution by Free Radicals. I. The Cleavage of Benzoyl Peroxide by the Triphenylmethyl Radical

โœ Scribed by Hammond, George S.; Rudesill, James T.; Modic, Frank J.

Book ID
126051671
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
434 KB
Volume
73
Category
Article
ISSN
0002-7863

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Radical-induced aromatic substitution be
Radical-induced aromatic substitution between benzoyl peroxide and benzenediols in the gas phase characterized by mass spectrometry
โœ Ya-Ping Tu; Ya-Qin Liu ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 333 KB

A radical-induced aromatic substitution mechanism for the reaction between benzoyl peroxide and benzenediols in the gas phase was characterized by mass spectrometry. The benzoyloxy radical produced from the hornolysis of benzoyl peroxide associates at its carbonyl group with the phenolic hydroxyl gr