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Free Radical Additions to 2-Methylenebicyclo[2.2.1]hept-2-ene 1

✍ Scribed by HUYSER, EARL S.; ECHEGARAY, GLORIA


Book ID
126322824
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
411 KB
Volume
27
Category
Article
ISSN
0022-3263

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Regioselective Radical Additions to 7-Ox
✍ Jean-Paul Vionnet; Kurt Schenk; Philippe Renaud πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 German βš– 658 KB

## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the