Addition of n-butyllithium to hydroxybicyclo[2.2.1]hept-2-enes
β Scribed by Richey, Herman G.; Wilkins, Cletus W.; Bension, Rouvain M.
- Book ID
- 126908715
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 877 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Radical addition to 7βoxabicylco[2.2.1]heptβ5βenβ2βone (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the
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