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Free-Radical Addition of Alkanethiols to Alkynes. Rearrangements of the Intermediate .beta.-(Vinylthio) Radicals

✍ Scribed by Benati, Luisa; Capella, Laura; Montevecchi, Pier Carlo; Spagnolo, Piero

Book ID
120710667
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
772 KB
Volume
59
Category
Article
ISSN
0022-3263

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Radicals / Addition 1 Stereoselectivity f Alkynes Alkanes can be added to alkynes in a thermally initiated freeradical chain reaction ("ane reaction"). The addition of cyclohexane to 1-alkynes la-1 yields a mixture of (4and (E)-2cyclohexyl-1-alkenes 3a-1. An essential step in this reaction is the ad