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Free energy hydride affinities of quinones in dimethyl sulfoxide solution

โœ Scribed by Cheng, Jinpei; Handoo, Kishan L.; Xue, Jieyou; Parker, Vernon D.

Book ID
127289410
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
560 KB
Volume
58
Category
Article
ISSN
0022-3263

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Hydride affinities of carbenium ions in
Hydride affinities of carbenium ions in acetonitrile and dimethyl sulfoxide solution
โœ Cheng, Jinpei; Handoo, Kishan L.; Parker, Vernon D. ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 739 KB

Hydride affinities of organic cations in solution, defined as the free energy change for the reaction (R+)s + (H-)s a (RH),, where the subscript s refers to the solvent, can be determined using either of two equations (eqs 5 and 7) derived from thermochemical cycles. The degree of uncertainty in AGh