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Free Energy Gap Dependence of the Electron-Transfer Rate from the Inverted to the Normal Region

โœ Scribed by Gayathri, N.; Bagchi, B.


Book ID
127209140
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
121 KB
Volume
103
Category
Article
ISSN
1089-5639

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WC h.vc mvcst~zrcd the dependence of rhc clcc~ronw I-actor III clccuon-tnnsfccr ra,e const.~nlr on tic cnmw gap and tcmpualurc by minimizing the clcctronic cncrgy wilh rcspcc~ to the mstanbncous non-equdbrmm solvent polar~~t~on. The clcctronic charge billows out and shrinks III rhc "normal" and slro