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Fragmentation of IsomericN-Quinolinylphthalimides on Electron Impact Ionization

✍ Scribed by Weisz, Adrian; Andrzejewski, Denis; Mandelbaum, Asher

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
303 KB
Volume
31
Category
Article
ISSN
1076-5174

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✦ Synopsis

The isomeric 2, 3-, 5, 6-and 8-quinolinylphthalimides give rise to different electron impact ionization mass spectra, which permit easy distinction. The specific fragmentation processes are rationalized in terms of proximity effects and stabilization of cyclic ion structures. Collision-induced dissociation spectra were used to support the proposed ion structures of major fragment ions.

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