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Fragmentation and carbonylation of dithioformate via addition of electrophilic alkynes to Fe(.eta.2-HCS2Me) complexes. X-ray crystal structure of FeCH(SMe)COC(CO2Me):C(CO2Me)S(CO)(PMe3)2

✍ Scribed by Touchard, Daniel; Dixneuf, Pierre H.; Adams, Richard D.; Segmueller, Brigitte E.


Book ID
126998739
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
416 KB
Volume
3
Category
Article
ISSN
0276-7333

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Transition-metal-substituted diphosphene
Activation of dithioformate by iron comp
✍ Dilip V. Khasnis; Nadine Pirio; Daniel Touchard; LoΓ―c Toupet; Pierre H. Dixneuf πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 896 KB

BH, containing iron complexes Fe(q'-HB(H),SCHSR')(CO)(PR,), (3) were prepared by reduction of Fe(q'-CS,R')(X)(CO)(PR& derivatives (2) with NaBH,. The X-ray structure of 3a (R' = R = Me) shows the cis addition of the H-and BH, fragments to the coordinated dithioformate C-S bond and that one B-H bond