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Fractionation of nitro and hydroxy polynuclear aromatic hydrocarbons from extracts of air particulates by supercritical fluid chromatography

✍ Scribed by Andrei Medvedovici; Frank David; Gilbert Desmet; Pat Sandra


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
228 KB
Volume
10
Category
Article
ISSN
1040-7685

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✦ Synopsis


Nitrated and hydroxylated polynuclear aromatic hydrocarbons nitro-. and hydroxy-PAHs extracted from air particulates were fractionated from other micropollutants by semipreparative packed-column supercritical fluid chromatography on silicagel. Sample injection and fraction collection was automated by means of a Gilson 233 XL sample preparation station. The collected fractions were analyzed by capillary gas chromatography᎐mass spectrometry operated in the ion-monitoring mode. For some specific solutes, concentrations down to the 1 pgrm 3 level could be measured. ᮊ 1998


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