Fourier transform Raman spectroscopic studies of a polyimide curing reaction
β Scribed by Jeffrey F. Aust; Melinda K. Higgins; Peter Groner; Stephen L. Morgan; Michael L. Myrick
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 861 KB
- Volume
- 293
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
β¦ Synopsis
Fourier transform (FT)_Raman spectroscopy was used to monitor the curing reaction of a polyimide bonding agent, the Ciba-Geigy Matrimid" system. Major Raman bands were assigned by comparison to spectra for small model mo&ules, by use of ab initio calculations, and by reference to previous literature. The set of FT-Raman spectra taken at various intervals during the curing process was modeled by principal component analysis (PCA).
Cure percentage determined by diierential scanning calorimetry was then regressed against scores on the first principal component for the different polymer samples. The PCA and regression results summarized significant trends in the IT-Raman spectra and led to a better understanding of the curing mechanism.
π SIMILAR VOLUMES
## Abstract Lithium perchlorate solutions in acrylonitrile (propenenitrile), in a range of concentration between 1 and 6 molal, were studied by using Fourier transform Raman spectroscopy. The new band in the __v__(CN) region proceeding from the bound species Li^+^β¦ (acrylonitrile)~__n__~ and the mo
An assessment is made of the applicability of Fourier transform (FT) Raman spectroscopy to the analysis of ancient human teeth from archaeological sites. Comparisons are made between the Raman spectra of nine modern adult and two exfoliate (deciduous) teeth and those of eight specimens of adult teet
The application of Fourier transform (FT) Raman spectroscopy to two pigment samples of mediaeval wall paintings and the identiΓcation of the pigments used are reported. The potential of FT-Raman spectroscopy as a non-destructive technique to examine valuable artistic and archaeological artefacts is