## Abstract The application of Fourier transform ion cyclotron resonance (FTICR) mass spectrometry to the quantitative study of molecular recognition in the gas phase is reviewed. Because most quantitative measurements are dependent on accurate determination of the pressure of a neutral reagent, me
Fourier transform ion cyclotron resonance study of the gas-phase basicity of N-nitrosodimethylamine
β Scribed by Maria E. Crestoni; Simonetta Fornarini
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 91 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1076-5174
- DOI
- 10.1002/jms.701
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The gas-phase reactions of the O -β’ radical anion with the halomethanes CH 3 X, CH 2 X 2 , CHX 3 , CX 4 , CF 3 X, CF 2 X 2 , CFX 3 (X = Br and Cl) and CXClBr 2 (X = Cl and F) have been examined at a low pressure (10 -5 -10 -4 Pa) with use of Fourier transform ion cyclotron resonance (FTICR) mass spe
The development of Fourier transform ion cyclotron resonance (FT-ICR) spectroscopy is traced from its 1973 conception by analogy to Fourier transform nuclear magnetic resonance (FT-NMR) spectroscopy and its 1974 experimental demonstration to its 1978 demonstration as the technique of choice for exam
## Abstract Liquid secondary ion mass spectrometry (LβSIMS) of six new functionalized macrocycles was investigated. All six compounds yielded abundant fragment ions and protonation molecular ions [M + H]^+^ under LβSIMS conditions. The proposed fragmentation mechanisms were supported by highβresolu