๐”– Bobbio Scriptorium
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Fourier transform infrared kinetic studies of the reaction of HONO with HNO3, NO3and N2O5at 295 K

โœ Scribed by Timothy J. Wallington; Steven M. Japar


Publisher
Springer Netherlands
Year
1989
Tongue
English
Weight
523 KB
Volume
9
Category
Article
ISSN
0167-7764

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๐Ÿ“œ SIMILAR VOLUMES


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The reactions of CCl, with O(,P) and O2 and those of CC1302 with NO have been studied at 295 K using discharge flow methods with helium as the bath gas. The rate coefficient for the reaction of CCI, with 0 was found to be (4.2 2 0.6) x lo-'' cm3/s and that for CCI3O2 with NO was (18.6 2 2.8) x lo-''

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Fourier transform infrared spectroscopy was used to identify and quantify products of the self reaction of ethylperoxy radicals, C2H502, formed in the photolysis of C12/C2H6 mixtures in 700 torr total pressure of synthetic air a t 295 K . From these measurements, branching ratios for the reaction ch

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The reaction of CzH502 with NO in helium carrier gas at 295 K with [He] = 1.6 X 1017 cm-3 has been studied using a gas flow reactor sampled by a mass spectrometer. Because no parent molecular ion or suitable fragment ion produced by CzH502 could be detected, the reaction was followed by measuring th

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Constants of the rawions of Cl with HIOz. IX&, 03, CH4, and HNC)J wertt mezxured at 295 K using a flaw discharge-mass spectrometric method. The rate consmts are, WpectiveIy, (6.2 ?c I.51 X 10qzS, (32&) x 10"tl, (1.3 -+. 0.3) X lo-'t, (1.2 ?t 0.3) X 10-13, and (6.8 t 3.4) X lO-is cm3/s.