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Four-Coordinate Mo(II) as (silox)2Mo(PMe3)2 and Its W(IV) Congener (silox)2HW(η2-CH2PMe2)(PMe3) (silox = tBu3SiO)

✍ Scribed by Kuiper, David S.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Cundari, Thomas R.


Book ID
111696096
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
417 KB
Volume
47
Category
Article
ISSN
0020-1669

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop