𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Formylation of ethylene ketals. Synthesis of α-monoalkyl ketals and ketones

✍ Scribed by Raymond D. Youssefyeh

Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
258 KB
Volume
5
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Regiospecific synthesis of α-methylene-k
Regiospecific synthesis of α-methylene-ketals and-ketones
✍ F. Huet; M. Pellet; J.M. Conia 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 153 KB

Synthetic routes to a(-methylene carbonyl compounds C\_ have received considerable attention (1 -4). Most of them involve either a p-elimination from Mannich

On cyclopentadienone-ketals and their di
On cyclopentadienone-ketals and their dimers. A novel rearrangement of α,β-unsaturated ketone dialkyl ketals
✍ Sarah Abramson; Jakov Zizuashvili; Benzion Fuchs 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 187 KB

The dimers(La & b) of dimethyl-and diethylcyclopentadienone ketals(la & b) undergo a novel 1,3-alkoxy-rearrangement to 4\_(a & b). Mild hydrolysis of 2 or 3 gives the monoketones (?a or b). On strong acid catalysed hydrolysis 2, 5. or 4 afford the cyciopentadienone-dimer(6) In contrast to the notor

Enantiomerically pure ketals in synthesi
Enantiomerically pure ketals in synthesis. Diastereoselective formation of β-keto and β-hydroxy ketals
✍ Clark N. Eid Jr.; Joseph P. Konopelski 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 283 KB

Enantiomerically pure acylketene acetals were employed to generate a homochiral p-keto ketal through a highly diastereoselective lithium enolate quench. The fi-keto ketal, which was also prepared through a desymmetrization ketulizution reaction on a meso dione, was employed in the synthesis of the i