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Formation of (η2-O2)Co(CO) and (η2-O2)Co(CO)2 by photolysis of Co2(CO)8 in dioxygen matrices at 20 K

✍ Scribed by Matthew J. Almond; Rachel H. Orrin


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
377 KB
Volume
444
Category
Article
ISSN
0022-328X

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Heterogeneous recombination of 0 + CO + GO, over a solid CO, surface at 77 K was investigated. A modified discharge flow setup was used to generate low 0 atom concentrations by the reaction N + NO + N, + O(3P). The 0 atom concentrations were measured upstream and downstream of the solid C02 substrat