Formation of α-silylvinyllithium reagents: Reactions of α-silyl- and α-stannyl-vinyllithiums with aldehydes and ketones
✍ Scribed by Terence N. Mitchell; Werner Reimann
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 514 KB
- Volume
- 281
- Category
- Article
- ISSN
- 0022-328X
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Several years ago we reported the preparation of u,B-epoxysulfones and studied their thermal and acid-catalysed rearrangement. [7) We have now investigated the possibi7ity that these compounds might serve as useful intermediates in the preparation of a-substituted aldehydes and ketones according to
A variety of a-chloromethyl, a,a-dichloromethyl, and a,o,u-trichloromethyl ketones were synthesized from aldehyde utilizing cathodic reduction as key reactions. Recently we have found a practically useful electroreductive anionic chain reaction in which aldehyde was efficiently converted into trich