Formation of Zr3+compounds in applied organozirconium catalysts and their role in the polymerization of ethylene
β Scribed by N. G. Maksimov; V. K. Dudchenko; V. F. Anufrienko; V. A. Zakharov; Yu. I. Ermakov
- Book ID
- 112362117
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 474 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-5760
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of β£-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of β£-olefins, a high reaction order with respect to ethy
## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = Ξ·~5~βC~5~H~5~), as a model for olefin polymerization with homogeneous ZieglerβNatta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c