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Formation of Zr3+compounds in applied organozirconium catalysts and their role in the polymerization of ethylene

✍ Scribed by N. G. Maksimov; V. K. Dudchenko; V. F. Anufrienko; V. A. Zakharov; Yu. I. Ermakov


Book ID
112362117
Publisher
Springer
Year
1978
Tongue
English
Weight
474 KB
Volume
14
Category
Article
ISSN
0040-5760

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## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = Ξ·~5~‐C~5~H~5~), as a model for olefin polymerization with homogeneous Ziegler‐Natta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c