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Formation of ion pairs in the Ziegler ethylene polymerization catalyst system Cp2Ti(Cl)CH2SiMe3-AlCl3

✍ Scribed by Eisch, John J.; Caldwell, Karen R.; Werner, Stefan.; Krueger, Carl.


Book ID
126140405
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
415 KB
Volume
10
Category
Article
ISSN
0276-7333

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The cationic transannular polymerization of cis,cis-l,5-cyclooctadiene (COD) initiated by Ziegler-Natta catalysts of the type Cp2MCI: (M = Ti, Zr, HI) with various alkylaluminium compounds, such as Et3A1, Et2AIC1 and Et3A12CI 3, was studied. The order of activity of these catalysts depends on the me