✦ LIBER ✦

Formation of water-soluble sulfonated azacalix[4]arenes from cyanuric chloride

✍ Scribed by Jonathan Clayden; Stephen J.M. Rowbottom; Michael G. Hutchings; Warren J. Ebenezer

Book ID: 104096547
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 210 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.04.068

No coin nor oath required. For personal study only.

✦ Synopsis

Addition of cyanuric chloride 2 (2,4,6-trichlorotriazine) to 4,6-diaminobenzene-1,3-disulfonic acid 1 gives a bis-triazine 3 which may be cyclised with diaminoarenes to yield water-soluble azacalix[4]arenes 5a-d. Alternatively, double substitution of chloride from the bis-triazine 3 yields new bis-triazine derivatives which may likewise be cyclised to functionalised azacalixarenes bearing functionalised side chains.

📜 SIMILAR VOLUMES

Synthesis of p-benzylcalix[4]arene and i

Synthesis of p-benzylcalix[4]arene and its sulfonated water soluble derivative

✍ Makha, Mohamed; Raston, Colin L. 📂 Article 📅 2001 🏛 Royal Society of Chemistry 🌐 English ⚖ 152 KB

Spectroscopic Studies of Brilliant Cresy

Spectroscopic Studies of Brilliant Cresyl Blue/Water-Soluble Sulfonated Calix[4]arene Complex

✍ Zhang, Yuling; Pham, Tuyet H.; Pena, Montserrat Sanchez; Agbaria, Rezik A.; Warn 📂 Article 📅 1998 🏛 Society for Applied Spectroscopy 🌐 English ⚖ 258 KB

Water soluble calix[4]arenes. A thermody

Water soluble calix[4]arenes. A thermodynamic investigation of proton complex formation

✍ Arena, Giuseppe; Cali, Rosario; Lombardo, Gaetano Giuseppe; Rizzarelli, Enrico; 📂 Article 📅 1992 🏛 Taylor and Francis Group 🌐 English ⚖ 462 KB

ChemInform Abstract: Synthesis of p-Benz

ChemInform Abstract: Synthesis of p-Benzylcalix[4]arene and Its Sulfonated Water Soluble Derivative.

✍ Mohamed Makha; Colin L. Raston 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Direct synthesis of calixarenes with ext

Direct synthesis of calixarenes with extended arms: p-phenylcalix[4,5,6,8]arenes and their water-soluble sulfonated derivatives

✍ Mohamed Makha; Colin L Raston 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 95 KB

p-Phenylcalix[4,5,6,8]arenes have been isolated from the base catalysed condensation of p-phenylphenol with formaldehyde in tetralin, and selectively converted to the corresponding sulfonated derivatives using sulfuric or chlorosulfonic acids.

Synthesis of water soluble molecular rec

Synthesis of water soluble molecular receptor from calix[4]arene-bis-crown-6

✍ Laurence Nicod; Stéphane Pellet-Rostaing; Frédéric Chitry; Marc Lemaire; Henri B 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 244 KB

Hydrosoluble Calix[4] arenes-bis-crown-6 2a, 3a and 3b have been synthesised in two steps via formylation and chlorosulfonylation of 1. Cs +-Ligand interactions were studied in aqueous media by UV-Visible analysis and showed a good affinity between receptor 2a and the caesium ion.