Even though Fe~ clusters in the gas phase have been demonstrated to be able to induce the cylotrimerization of added C2H 2 ligands to benzene, the precursor ion Fe4(CzH2) ~ has not yet been structurally characterized. To improve our understanding of this type of ion, we compare the products obtained
Formation of the dimer cation (C6H6)2+ in gaseous benzene
โ Scribed by E.G. Jones; A.K. Bhattacharya; T.O. Tiernan
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 948 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0020-7381
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The van der Waals complex benzene-SF, has been studied theoretically by ab initio calculations using MP2 theory. A C, symmetry has been found for the equilibrium configuration in contrast to the Cs, symmetry derived using a pairwise atom-atom Lennard-Jones potential. Thus, good agreement has been ac
## Abstract [LiN(SiMe~3~)Ar]~2~ (1, Ar = 2,6โ__i__Pr~2~C~6~H~3~) is prepared by the reaction of HN(SiMe~3~)Ar with __n__BuLi in __n__โhexane. This compound with an unusual structure contains a fourโmembered [LiN]~2~ heterocycle with two solventโfree twoโcoordinate Li centers. Its molecular structur