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Formation of novel molybdenum and tungsten sulfides by reduction of MoS2 and WS2: A new route to chevrel phases

✍ Scribed by K.S. Nanjundaswamy; J. Gopalakrishnan


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
261 KB
Volume
68
Category
Article
ISSN
0022-4596

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop