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Formation of highly caged compounds through Diels—Alder cycloaddition of 3-bromo-7-(bromomethyl)tetracyclo[5.3.1.02,6.04,8]undeca-10(12)-ene-9,11-dione with itself and with cyclopentadiene

✍ Scribed by Uma Sudhir; S. Joly; Beena James; Mangalam S. Nair; Nigam P. Rath

Book ID
111759702
Publisher
Springer Netherlands
Year
2004
Tongue
English
Weight
163 KB
Volume
30
Category
Article
ISSN
0922-6168

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Two fascinating rearrangements through s
Two fascinating rearrangements through selective placement of bromine substituents. Photochemical synthesis of 3-bromo-7-(bromomethyl) tetracyclo[5.3.1.02,6.04,8]undec-10(12)-ene-9,11-dione and its rearrangement with amines
✍ Mangalam S Nair; Uma Sudhir; S Joly; Nigam P Rath 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 426 KB

A novel entry into 3-bromo-7-(bromomethyt)tetracyclo[5.3.1.02"6.04"S]undec~10(12)-ene-9,11-dione, which readily undergoes further rearrangement with primary amines, has been developed through photolysis of 2,5bis(bromomethyl)tricyelo[6.2.1.02"7]undec-4,9-diene-3,6-dione.