𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Formation of gem-dinitrates from acetaldehyde and trifluoroacetaldehyde

✍ Scribed by Kacmarek, Andrew J.; Jarke, Frank H.; Shamir, Jacob; Solomon, Irvine J.; Lustig, Max

Book ID
126840728
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
566 KB
Volume
40
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Pyrolysis of trifluoroacetaldehyde. The
Pyrolysis of trifluoroacetaldehyde. The formation of trifluoromethane and hexafluoroethane
✍ Michael T. H. Liu; Leon F. Loucks; David G. Hooper πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

## Abstract The thermal decomposition of trifluoroacetaldehyde at temperatures f 471 to 519Β°C has been studied by measuring the rates of formation of CF~3~H and C~2~F~6~. It is concluded that the high‐pressure reaction mechanism involves a Rice‐Herzfeld reaction scheme with first‐order initiation a

Competitive bicyclobutane and allene for
Competitive bicyclobutane and allene formation from phenyl-substituted gem-dibromocyclopropanes
✍ William R. Moore; John B. Hill πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 168 KB

Tetraalkylsubstituted E-dibromocyclopropanes react with methyllithium to afford bicyclobutanes rather than allenas.' The intermediate cyclopropylidenes, free or complexed, must suffer sufficient steric hindrance to opening that insertion into an alpha CH bond takes precedence.'c Any factor which wil