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Formation of ethers from ozonides by reductive cleavage of the two carbon-oxygen bonds of the peroxide bridge

✍ Scribed by Fujisaka, Tomohiro; Nojima, Masatomo; Kusabayashi, Shigekazu

Book ID
120879861
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
391 KB
Volume
50
Category
Article
ISSN
0022-3263

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The cleavage of two carbon-carbon bonds
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The reaction of dispiro[cyclopropane-l,l'-indan-3',1"-cyclopropane]-2'-one (1) under Wolff-Kishner conditions gives spiro[cyclopropane-l,l'-indan] (2) in which the ketone has been reduced and two bonds of one cyclopropane ring have been cleaved. The Wolff-Kishner reaction is a classic method for