The stereoselective reduction of a-keto esters/a-keto amides, which have various chiral auxiliaries using SmI 2 , is examined. 2(S)-Methoxymethylpyrrolidine, 1,1,2(S)-and 1,1,2(R)-triphenylethanediol were found to be suitable chiral auxiliaries that produced the corresponding a-hydroxy ester and ami
Carbon-carbon bond formation by the reduction of dienic esters
✍ Scribed by Curini, Massimo; Coccia, Rita; Ceccherelli, Paolo; Halls, Timothy D. J.; Porter, Barry; Wenkert, Ernest
- Book ID
- 125901275
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 462 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
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