Formation of Desoxybenzoin in the Borohydride Reduction of the Reaction Mixture of Benzoin with Thionyl Chloride and Pyridine *
β Scribed by Okumura, Yasuaki; Masui, Shohei
- Book ID
- 127215105
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 404 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
In the course of an investigation of solvent effects on the relative reactivities of ketones with borohydridel, we have observed some unusual features of reductions in pyridine solvent which are relevant to recent discussions of the mechanism and stereochemistry of metal hydride reductions2,3,4,5 an
1) We have been Investigating new types of reactions with sodium borohydrlde, the reagent, a combination of sodium borohydrlde and pyrldlne, showed a very Interesting reaction. The reduction of amides with this ed ra)ig) to give the corresponding amlnes and nltrllea by authors (S.Y. and Y.K.). In th